Far-Infrared Properties And Testing Of Textiles
Development of far infrared textiles
Survey
In the field of textile and clothing, the developed countries in Japan, the United States, Germany, Russia and other developed countries first launched the applied research on far-infrared technology, and promoted the development of far-infrared textiles.
Especially in Japan, the related patents of far infrared fiber products in the mid 1980s have springing up in Japan, forming a boom in developing far-infrared functional textiles.
The Japanese bell spinning company uses ceramic powder to infiltrate nylon or acrylic polymers to spin the "Massoni J N" and "Marceau Nik A" far-infrared fibers respectively. The Asahi chemical company uses zirconium carbide ceramic solution coating to develop a new nylon thermal fabric "SOLAR-V", which is mainly used for snow sweaters.
China began developing far-infrared textiles in 1990s.
The Jiangsu Textile Research Institute has developed far-infrared polyester staple fiber. The far-infrared polypropylene fiber developed by Tianjin University of Technology has good moisture conductivity, low price, light weight, and good antibacterial and anti moth properties.
At present, the far-infrared textiles developed mainly use ultrafine ceramic powders as additives to prepare far-infrared fibers in spinning solution, or finishing liquid made of ceramic powder.
The main application of ceramic powder: metal oxides, such as Al2O3, TiO2, BaO, ZrO, SiO2, and so on; metal carbides, such as SiC, TiC, ZrC, etc.
Nitrides
Such as BN, AlN, ZrN and so on.
Far infrared textiles
Mechanism
1. far-infrared ray
Infrared is located between visible and microwave, and the wavelength range of infrared is very wide. It will be divided into three wavelengths in science: near infrared band: 0.77~3 m; mid infrared band: 3~30 m; far infrared band: 30~1000 m.
Due to the narrow range of the mid infrared band, the mid infrared band is incorporated into the far-infrared band in the field of health care.
2. mechanism of action
Thermal radiation is a heat pfer method characterized by the pmission of energy in the form of electromagnetic waves.
Thermal radiation mainly includes ultraviolet, visible and infrared rays.
According to Kirchhoff's law, a good radiator must be a good absorber, that is, the ability of an object to radiate heat is strong, and its absorption capacity is also strong, which is directly proportional to the two.
The human body can radiate far infrared rays and absorb far infrared radiation.
As the body 60%~70% is water, according to the matching absorption theory, when the wavelength and the infrared radiation are
irradiation
When the absorption wavelength corresponds to the object, the molecules absorb resonance.
The main wavelength of the thermal radiation emitted by the human body is about 10 m. Far-infrared textiles radiate the far-infrared rays of 3~25 m after absorbing the external energy, which is consistent with the infrared rays absorbed by the human body, and can form resonance.
Far infrared textiles absorb the infrared wave energy from human body and feed them back to the human body, which improves the skin temperature and achieves the purpose of heat storage and warmth retention.
The heat absorbed by the skin can be pferred through the medium and blood circulation, so that the heat energy reaches the body tissue to achieve the effect of health care and auxiliary medical treatment.
Far infrared textiles generally improve the pmitting power by increasing the surface emissivity.
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3. function
Far infrared textiles mainly have thermal insulation function, namely, heat preservation function, health care function and antibacterial function.
Far infrared textiles, due to the addition of far infrared radiation materials with high emissivity, their thermal insulation performance is to use the thermal radiation of organisms to absorb and store the energy of external radiation to organisms, so that organisms can produce "greenhouse effect" to prevent heat loss and good thermal insulation effect.
Therefore, far-infrared fabrics have remarkable thermal insulation function and are suitable for making winter clothing with cold resistant fabric and light weight.
The heat absorbed by the skin can be passed through the media.
Blood circulation
It can promote the blood circulation and metabolism of the human body. It has the functions of eliminating fatigue, restoring physical strength and relieving pain symptoms, and has some auxiliary medical effects on body inflammation.
Therefore, far infrared products have certain symptoms improvement and adjuvant treatment effects on diseases caused by blood circulation or microcirculation disorders.
Suitable for making underwear, socks, bedding, kneecap, elbow protector, wrist protector and so on.
The addition of particulates in fiber can make the fiber surface porous, the surface area increased, and the adsorption and diffusion characteristics of surface activity and surface state are improved obviously, so that the product has the functions of sweat absorption, deodorization, sterilization and so on.
The bacteriostatic test showed that far infrared textiles had a bacteriostasis rate of 95% against Staphylococcus aureus, Candida albicans, E. coli and other pathogens.
Testing methods and related standards
1. standard
At present, the functional testing standards for far-infrared textiles are mainly national standard GB/T18319 - 2001, test methods for infrared thermal storage and thermal insulation of textiles, textile industry standard FZ/T64010 - 2000 far-infrared textiles, China Standard Association standard CAS115 - 2005 health care functional textiles.
The GB/T18319 - 2001 standard stipulates that the infrared reflectance and pmittance of textiles can be determined by infrared radiometer, the absorptivity is calculated, and the heating rate of irradiation is determined by point thermometer.
Mainly from the infrared absorption rate and infrared radiation heating rate two aspects of testing and evaluation.
The FZ/T64010 - 2000 standard specifies the technical requirements, test methods, inspection rules, result determination and instructions for use of far-infrared textiles.
This standard uses the normal emissivity as the evaluation index of far-infrared textile far-infrared function, and deducts the normal emissivity of the contrast sample (the corresponding non far infrared product) with the normal emissivity of the sample as the normal emissivity to raise the value.
The experimental instruments are infrared spectrometer and blackbody furnace.
Finally, the normal emissivity calculated is the normal emissivity of the 8~15 M band.
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CAS115 - 2005 standard adopts the method of determining the normal emissivity, and has developed the far infrared function evaluation index. It is the only standard applicable to health care functional textiles in China at present. Among them, the part of the textile with far infrared function has standardized its terminology definition, test method, result judgement and sign, etc. it is suitable for the far-infrared normal emissivity detection of far-infrared normal materials with various emissivity of more than 0.2 and heat conduction objects.
The normal emissivity of the sample is measured by the method of sample temperature at 100 C, comparing the full radiation brightness with the standard blackbody method at the same temperature to the full radiance.
The test instruments include infrared spectrometer (or infrared radiometer) and blackbody furnace.
The computer processed the radiant intensity of the blackbody furnace, the radiance of the sample and the radiance of the contrast sample, and calculated the normal emissivity of the 4~16 M band.
The comparison of the three standards is shown in Figure 1.
Fig. 1 Comparison of three standards
2. test indicators and methods
The main function of far-infrared textiles is thermal insulation, so its thermal insulation performance is the main test index.
For far infrared textiles, the index of far-infrared performance is mainly emissivity and temperature rise.
The main indicators of health function are blood microcirculation.
Health indicators are additional functions only when they are required.
(1) emissivity
As long as it is not absolute zero, any object can radiate infrared electromagnetic waves.
The index of far-infrared radiation energy is radiation power and radiance. But in practical applications, emissivity is often used to characterize it.
Emissivity refers to the ratio of radiated power (or radiance) of a sample to the radiative power (or radiance) of a blackbody at a certain temperature within a wavelength interval.
The emissivity is a positive number between 0~1.
The general emissivity depends on material properties, environmental factors and observation conditions.
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The emissivity can be divided into hemispherical emissivity and normal emissivity.
The hemispherical emissivity is divided into hemispherical total emissivity, hemispherical integral emissivity and hemispherical spectral emissivity. The normal emissivity is divided into normal total emissivity and normal spectral emissivity.
At present, the far-infrared performance of products is measured by normal emissivity in the world.
The far-infrared emissivity was determined by Fourier pform infrared spectroscopy.
There is no uniform test method in Tianjin. The spectral emissivity of Tianjin is measured and the total emissivity of the method is measured.
A blackbody is an object that absorbs any radiation at any wavelength without any reflection.
According to Kirchhoff's law of radiation, at a certain temperature, the blackbody is the largest body of radiation. Its reflectivity is 0, its absorptivity is 100%, and the emissivity equals 1. It can be called a complete radiator.
There is no real blackbody in reality, it is only approximate.
The emissivity of an object is related to temperature. The temperature must be specified when describing the emissivity of the fabric.
(2) Wen Shengfa
Temperature rise method is used to measure the change of fabric temperature under certain conditions and time. The temperature rise method is simple and can directly reflect the temperature rise of fabrics.
The temperature rise method includes infrared thermometer method and stainless steel pot method.
Infrared thermometer means that the same temperature, 20 humidity and 60% relative humidity are used to irradiate common fabrics and far-infrared fabrics of the same specification and structure. The temperature of two fabrics at different time intervals is irradiated by infrared light, and then the difference is found. The stainless steel pot means a stainless steel cylinder with a height of 30cm and a volume of 250mL. The upper and lower bottom of the cylinder is made of foam plastic, and the thermometer is inserted on the cover. The fabric is coated outside the stainless steel cylinder, and the temperature of two fabrics is measured under the infrared lamp, and then the difference is obtained.
Zhang Ping chooses the fabric with different concentration finishing liquid and the far-infrared fabric with different fabric structure to conduct temperature rise test. In the pure cotton plain cloth sample, the higher the concentration of the finishing agent, the faster the temperature rises with the time.
The results show that the temperature rise method reflects the thermal effect of far-infrared fabrics absorbing far-infrared rays.
Far infrared
Functional evaluation
For the functional evaluation of far-infrared textiles, we should set up an evaluation system with emissivity as the main body and temperature rise and human test as auxiliary.
The functional evaluation of fabrics can be carried out in the following aspects: first, directly test the emissivity of textiles; two, use external means to effect textiles, and test their changes, such as temperature rise method; three, the human body test method, the effect of fabric on human body, and the effect of testing on human body.
Conclusion
Since the twenty-first Century, the far-infrared functional textiles industry has developed rapidly and has a wide variety of products. However, the industry has been short of technical specifications and related standards. There is no uniform standard for far-infrared textiles evaluation.
Therefore, it is necessary to strengthen basic research on far-infrared textiles testing methods and evaluation criteria.
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