High Performance Fiber PTFE Witness The Wisdom Of Chinese People
High performance
Teflon
(PTFE) fiber materials have excellent high and low temperature stability and chemical stability.
Electrical insulation
Non adhesion, weather resistance, flame retardancy, self lubrication and other properties have been widely used in the national economy.
field
It has been widely applied in many fields, such as environmental protection, filtration, construction, aerospace and so on.
Due to the nature of polytetrafluoroethylene, P
TFE fiber
Manufacturing can not simply use the molding method of general thermoplastic polymer materials (such as extrusion molding), and this technology bottleneck is also an important reason why our country can not produce PTFE fiber for a long time. The research and development personnel of the project independently developed and produced the polytetrafluoroethylene fiber by the membrane splitting method. That is, first, we can prepare the PTFE film that satisfies certain conditions through the three-dimensional stretching method. After the PTFE film is cut, then the PTFE fiber can be made through a certain stretching and heat treatment process.
Breaking the technology of developed countries
blockade
According to Dr. Hao Xinmin, a senior engineer of the general military equipment research institute, who participated in the research and development, PTFE is insoluble in any solvent, and the macromolecule chain is arranged in a straight line, with a rigid rigidity and above melting point.
Large viscosity
It is difficult to use traditional solution or melt spinning. This has become a major technical problem in the field of deep processing of PTFE materials, and has also become the application technology of PTFE materials in China.
bottleneck
。
At present, only a few companies in the world have mastered the production technology of PTFE fiber. The main production processes include carrier spinning and paste extrusion. However, these companies have long been technically blocked in China, and the products are expensive, which greatly increases the application cost of PTFE fibers, thus seriously restricting the development and application development of PTFE fibers.
Starting from the analysis of only a few samples of foreign production, a long years of hard exploration and hard work began.
據悉,由企業、科研單位和用戶組成的課題組研究設計了PTFE膜裂法長短纖維生產工藝流程,研發了溫度梯度控制的非等速、變幅寬、多次拉伸PTFE纖維的生產工藝,研制了高強異型PTFE長纖維和短纖維,解決了PTFE短纖維“併絲”問題;研制了多棱角型膜裂長纖維切刀、耐磨金剛石短纖維分切針輥、牙線膜裂切片成型等關鍵裝置,設計加工了螺旋式擠壓機、二輥壓延機、非等速拉伸機、梯度溫控變幅寬拉伸機、膜裂長纖維分切機、短纖維分切機、纖維擠壓牽伸機、卷曲機等系列成套生產設備,并建立了規模化生產線;研發生產了“ひ”形PTFE牙線、高強純PTFE梯度覆膜過濾材料,所有這些工藝技術、系列產品及生產設備,在國內外未見相似或相同文獻報道,具有新穎性和創新性。
The product novelty search further proves that the PTFE fiber produced has filled the domestic blank. The PTFE fiber performance is at the international leading level, and the PTFE fiber application product is in the international advanced, the domestic leading level.
Production capacity of 1000 ton class has been formed.
The expert appraisal committee of this appraisal activity is a strong lineup. The director and deputy director of the appraisal committee are respectively three academicians from Sun Jinliang, Jiang Shicheng and Zhang Yaoming. The 11 well-known experts from the fields of chemical fiber materials, industrial textiles, environmental protection and chemical industry all agree that the project is a major integrated innovation in China's high-performance fiber processing technology, production equipment, product development and other aspects, with demonstration effect, and the overall technology has reached the international advanced level.
In the opinion of experts, experts believe that the project has invented PTFE uniform solid processing and membrane making technology, and the PTFE film and fiber integrated production equipment with independent research and development and integrated innovation have been running steadily, and the production capacity has reached 1000 tons.
The research results have 10 independent intellectual property rights, applied for invention patents, and have authorized 4 items. The social and economic benefits are significant, and the market has broad application prospects.
Ye Yongmao, consultant and senior professor of the China Chemical Fiber Industry Association, told reporters: "the national development and Reform Commission has clearly listed the development and production of PTFE fiber and products in this year's guidance catalogue for industrial restructuring." in the year 12th Five-Year, we can see that the series of fruitful achievements of project completion units is exciting. "
PTFE fiber as an excellent skeleton material, its mass production can promote the application of high performance fiber such as aramid fiber 1313, polysulfonamide fiber and polyphenylene sulfide fiber on filter material. It can accelerate the pformation of China's chemical fiber industry's economic development mode, and promote the restructuring of chemical fiber industry.
Optimization and upgrading
We should improve and develop the modern industrial system.
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Ye Yongmao introduced the production of PTFE fiber by membrane cracking and its application products, mainly including polytetrafluoroethylene long fiber and PTFE short fiber. The products developed by PTFE long fiber include: long fiber yarn, PTFE sewing thread, polytetrafluoroethylene dental floss, polytetrafluoroethylene long fiber reinforced polytetrafluoroethylene network reinforced by chlor alkali engineering, polytetrafluoroethylene fabric produced by PTFE fiber, PTFE film coated needle felt filter material and so on.
The technology of Teflon long and short fiber produced in this project is at the international advanced level. The price of the product is about 35% of the foreign similar products, which greatly reduces the production cost of the domestic users, laying the foundation for the batch application of high-performance PTFE fiber in China's environmental protection.
Ideal material for dedusting filter material
Fang Aimin, director and senior professorship engineer of the dust removal and ash removal Research Institute of Guodian Environmental Protection Research Institute, said: "the breakthrough of domestic PTFE fiber production technology has successfully broken the monopoly and technology blockade of foreign products to us over the years, which will lead to the upgrading of environmental technology and materials. It is of great social significance and important significance in the key stage of the" blue sky project "in 12th Five-Year.
Economic performance
"
According to Fang Aimin, the important application of PTFE fiber in the project is to prepare PTFE filter material for high temperature corrosive flue gas dedusting.
At present, the domestic PTFE filter has been widely used in waste incineration, coal-fired power plants, steel and other industries. It is one of the key materials for energy saving and emission reduction in China. At the same time, PTFE filter material can also be used in the gas-solid two phase separation field under corrosive high temperature environment as filtration separation material.
At present, there are about more than 40 municipal solid waste incinerators and hazardous solid waste incinerators in China, all of which are made of PTFE long and short fiber products developed by this project. The total filtration area is above about 700000 square meters, and the total amount of PTFE fiber used is about 595.31 tons. In, the total amount of fiber used in our country is about 595.31 tons.
For example, in the whole year of 2009, the PTFE long fiber used in the filter material used for producing garbage incinerator is 40 tons, and the amount of short fiber reaches 240 tons, which accounts for more than 91% of the total waste incineration industry.
In the power industry, 9 household electrical appliances factories have used the PTFE long fiber filter bag foundation cloth produced by this project, with a total area of 24.
50 thousand square meters, the total weight of PTFE fiber is about 36.75 tons.
Teflon base cloth provides key support for the 30000 hour filter material life in China's power industry. The market share is over 50%.
The continuous use of pure PTFE fiber membrane filter material is as high as 250 degrees centigrade, and the instantaneous working temperature reaches 280 degrees.
The service life is as long as 4 years, far exceeding that of ordinary membrane filter media.
According to the introduction, PM2.5 refers to particles in the atmosphere whose diameters are less than or equal to 2.5 microns, also known as particulates, which have important effects on air quality and visibility.
Compared with the coarser atmospheric particles, PM2.5 has a small particle size, rich in toxic and harmful substances, and has a long residence time and a long distance in the atmosphere. Therefore, it has a greater impact on human health and atmospheric environmental quality.
In most parts of China, especially in North China where industrial concentration is concentrated, PM2.5 accounts for more than half of the total weight of airborne particulate matter.
PM2.5 is also the main cause of haze weather, but in the past, there was no PM2.5 in China's air quality standards.
The Ministry of environmental protection recently issued the "weight method" for determining PM10 and PM2.5 in ambient air. For the first time, the determination of PM2.5 in suspended particles in air with diameters less than or equal to 2.5 microns was standardized.
The filtration efficiency of PM2.5 using polytetrafluoroethylene and its coated filter media is as high as 99.99%.
All of these have made great contributions to the implementation of the policies and guidelines for energy conservation and emission reduction in China, making our country in the key area of PTFE filter material no longer controlled by others and saving the cost of environmental protection investment for the country.
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