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    Basic Thinking And Technological Process For Processing Cattle Soft Upper Leather

    2010/3/23 15:50:00 99

    Process Flow Of Yellow Cattle Soft Upper Leather

    Abstract: Based on the production practice, the process control conditions in the wet processing of yellow cattle soft upper leather were introduced in detail.


     

    Key words: yellow cattle hide; soft upper leather; Technology


     

    Chinese map classification number:

    TS543

    Document identification code:

    A

    Article number:

    1671-1602

    (

    Two thousand and nine

    )

    01-0003-02


     

    One

    Introduction


     

    Yellow cattle soft upper leather is an important part of the leather market. The casual shoes and tube boots designed and made are fashionable and comfortable, and are very popular with consumers.

    In the market, the requirements for cattle soft upper leather are characterized by full body, good bone, soft, elastic, extensibility and plasticity. The leather surface is smooth and meticulous, without cracks, wrinkles and loose surfaces. The leather is clean and greasy, with uniform color and bright color. The thickness is uniform and smooth.

    This article will introduce the processing technology of yellow cattle soft upper leather.


     

    Two

    Basic thinking and technological process for processing cattle soft upper leather


     

    The basic idea is to start from the word "soft" and achieve "soft but not loose".


     

    Technological process: wet blue sorting

    -

    Horizontal extrusion

    -

    Soft throw

    -

    Shaving

    -

    Trimming

    -

    Weigh

    -

    Degreasing

    -

    washing

    -

    Retanning

    -

    neutralization

    -

    Two Retanning

    -

    dyeing

    -

    Fatliquoring

    -

    washing

    -

    Water stretch

    -

    vacuum drying

    -

    Hanging drying

    -

    Sprinkler regain

    -

    Oscillating stretch

    -

    toggling

    -

    Selection classification

    -

    Trimming

    -

    Finishing


     

    Three

    Technical points and process implementation of processing cattle soft upper leather


     

    Three point one

    Sorting of wet blue skin


     

    Wet blue sorting is to better control the production and ensure the quality of products, and is also the basis of "looking at the skin to make leather".

    Choose the same way, the quality is better, the size of the sheet is large, the grain is less damaged, the wrinkle is less, the location is small, the handle is soft, the plump is good, the grain is smooth and meticulous, the color is uniform is the shallow lake blue wet leather.


     

    Three point two

    Preparation before wet processing


     

    After selecting wet blue leather, the horizontal expansion is carried out through a through water extruder.

    Then, through the soft tumbling effect of the drum, the wrinkle of the leather surface is eliminated, and the leather is soft, and the water content of each part is uniform.

    Cutting thickness control

    One point one

    ~

    1.2mm

    The thickness is uniform.

    Then fix useless corners and cut them into round ends.

    Finally, the wet blue leather is accurately weighed as the basis of material in the later process.


     

    Three point three

    Returning humidity


     

    Before the retanning, the wet blue leather must be fully wetted, so that the leather fibers can be restored to the naturally stretched knitting state, laying a good foundation for the infiltration and combination of the chemical materials in the subsequent process.

    Technology:

    Two hundred

    % water (

    Thirty-five

    ~

    Forty

    Temperature)

    Two

    Oxalic acid,

    Zero point five

    %

    AD

    Turn

    60min

    measure

    PH

    =

    Three point five

    ~

    Three point eight

    Wash it.


     

    Oxalic acid is added to the process to strengthen the rinsing of wet blue leather, remove the surface of the blue leather with too much chromium salt, and soften the grain and improve the handle.

    AD

    It is a non-ionic surfactant, which can help blue leather degrease and get wet.


     

    Three point four

    Retanning


     

    In order to further improve the shrinkage temperature of leather, reduce the loose face, split surface and rough surface of blue leather, give leather soft handle and good fullness.


     

    Technology:

    One hundred

    % water (

    Thirty-five

    Temperature)

    One

    %

    AF135

    Turn

    10min

    ,

    Three

    %

    Ter

    -

    GotanTSP

    ,

    Two

    %

    TergotanPR

    Turn

    60min

    ,

    Zero point three

    % formic acid, turn

    30min

    Measure

    PH

    =

    Three point eight

    ,

    Two

    %

    TanicorCSD

    ,

    Six

    % chromium powder.

    B

    =

    Thirty-three

    %)

    One

    %

    CatalixU

    Turn

    90min

    ,

    One

    Sodium formate, turn

    30min

    ,

    Zero point eight

    % sodium bicarbonate, added in two times, each interval.

    30min


     

    measure

    PH

    =

    Four point one

    Stop the drum for the night and turn the next morning.

    30min

    Wash it.


     

    among

    AF135

    It is a black dye.

    Prior to retanning, the dyed leather is pre dyed to increase the surface blackness of the leather.

    TergotanTSP

    It is a polymer of organic resin, which can give leather meticulous, firm grain and excellent softness.

    TergotanPR

    It is an acrylic resin, which has a good filling effect on loose leather belly.


     

    Selection of chrome containing synthetic tanning agent

    TanicorCSD

    Cationic fatliquoring agent

    CatalixU

    Good retanning effect can be obtained by using chromium powder.

    TanicorCSD

    Good permeability, easy to be absorbed by leather, and uniform and bright dyeing effect.

    adopt

    CatalixU

    The lubrication can prevent the leather from winding in the drum, enhance the tensile strength and tear strength of the leather, disperse the chrome tanning agent, and disperse the natural oils and fats.


     

    Attention should be paid to the amount of chromium powder in Retanning Process.

    Six

    Under the premise of ensuring tanning, the skin surface is thickened and the location difference is increased.

    After retanning, the caustic soda is slowly extracted in the original bath.


     

    Three point five

    neutralization


     

    Proper control of neutralization degree and time should be paid attention to in the following aspects.


     

    (

    One

    Liquid ratio.

    The liquid ratio is too small, it is easy to cause skin entangling, some leather is easily torn, and it will cause uneven leather, so the liquid ratio should be controlled.

    One point five

    Above.


     

    (

    Two

    Temperature.

    General control

    Thirty-five

    At high temperature, the temperature is too high to make the skin surface excessive, and the skin is not pparent.


     

    (

    Three

    The choice of neutralizer.

    In order to achieve good neutralization effect, neutralization initial selection

    Clariant

    Company

    TanicorAPR

    It has good cushioning effect, little influence on the alkalinity of chromium complex and moderate and moderate neutralization effect.

    After neutralization buffer bath was formed, two neutralization agents, sodium formate and sodium bicarbonate, were added.

    The combination of these two neutralizer can compensate each other's shortcomings and achieve good neutralization effect.


     

    (

    Four

    Neutralization time.

    In order to make the internal and external neutralization uniform, the neutralization time is controlled.

    Eighty

    ~

    90min


     

    Technology:

    One hundred and fifty

    % water (

    Thirty-five

    Temperature)

    Two

    %

    TanicorAPR

    Turn

    20min

    ,

    One point five

    Sodium formate,

    Zero point three

    % sodium bicarbonate

    60min

    Measure

    PH

    =

    Five

    Wash thoroughly and remove some soluble salts from the leather to avoid frost.


     

    Three point six

    Retanning, filling and dyeing


     

    The style of cattle soft upper leather requires retanning to keep leather soft and firm.

    Through the preceding process, some properties of cattle soft upper leather have been initially reflected, but the fullness of the belly and the whole is still insufficient, and the grain is not firm enough and meticulous.

    In view of these phenomena, the following kinds of materials are mainly selected.

    TergotanESN

    Acrylic Retanning Agent has good filling performance.

    TergotanPMB

    The compound polymer resin retanning agent makes the grain surface firm and meticulous.

    TergotanRSN

    Amino resin retanning agent has a good filling effect on side edges.

    TanicorSG

    Alternative synthetic tanning agent can improve the fullness of leather; soft wattle tannin extract is used to enhance the fullness and elasticity of leather.

    In the process of retanning, proper use of some grease can make the whole skin feel the same.


     

    Yellow soft shoe upper leather requires deep dyeing and uniform and bright colors.

    Dyes with good fastness, sweat resistance and light resistance should be selected.

    Some disperse tannins are used in dyeing.

    CoralonOT

    It can help the leather to obtain good dyeing effect.


     

    Technology:

    One hundred

    % water (

    Thirty-five

    ~

    Forty

    Temperature)

    Two

    %

    TergotanTSP

    Turn

    20min

    ,

    One

    %

    DerminolCFS

    Turn

    10min

    ,

    Two

    %

    TergotanESN

    ,

    Three

    %

    Ter

    -

    GotanPR

    Turn

    50min

    ,

    Two

    %

    GF

    (black dye)

    One

    %

    CoralonOT

    Turn

    30min

    ,

    Three

    %

    MimosaFS

    ,

    Three

    %

    Tani

    -

    CorSG

    ,

    Five

    %

    TergotanRSN

    ,

    One

    %

    DerminolCFS

    Turn

    60min

    ,

    Zero point five

    % formic acid, turn

    30min

    Wash it.


     

    Three point seven

    Main fatliquor


     

    In order to meet the requirements of yellow cattle soft leather, it is necessary to use fatliquoring materials reasonably, so as to lubricate and protect leather fibers while improving physical and mechanical properties of leather, such as elongation, tensile strength and tear strength.

    The amount of oil is controlled.

    Eleven

    % ~

    Twelve

    The choice of fatliquor varieties should not be too simple.

    Three

    ~

    Four

    Species.

    Pay attention to the following questions in operation.


     

    (

    One

    Liquid ratio.

    The small liquid ratio can accelerate the penetration and diffusion of emulsion, which is beneficial to improve the absorption of fatliquoring agent. The disadvantage is that it has strong effect on leather machinery and vulnerable to damage to grain.

    So the liquid ratio should be larger.


     

    (

    Two

    Temperature.

    Temperature control in

    Fifty

    ~

    Fifty-five

    It is conducive to emulsification, permeability and absorption of oils and fats.


     

    (

    Three

    Time.

    In order to ensure the full penetration and dispersion of fatliquoring agents, time is controlled.

    Sixty

    ~

    90min

    When the fatliquoring agent is absorbed, the oil is added with acid.


     

    Technology:

    Two hundred

    % water (

    Fifty-five

    Temperature)

    Two

    %

    DerminolNLM

    ,

    Two

    %

    DerminolNKS

    ,

    Two

    %

    DerminolSU-10

    ,

    Two

    %

    DerminolCFS

    Turn

    60min

    ,

    Two

    Formic acid, two times after dilution, each interval.

    30min


     

    DerminolNLM

    It is a kind of lecithin, which gives leather soft handle and smooth and moist grain.

    DerminolNKS

    It is a kind of cow's foot oil, which helps to improve leather compactness and tear resistance.

    DerminolSU10

    It is a compound fatliquoring agent that makes leather soft and plump.


     

    Three point eight

    Wet finishing


     

    After retanning and fatliquoring, static water control and proper prolonging of static time are favorable for material distribution inside leather.

    Then the following processes are carried out:


     

    (

    One

    Squeeze and stretch.

    It is required to stretch out and stretch, and the whole leather is smooth without dead ends.


     

    (

    Two

    Vacuum drying.

    Put the meat of the billet on the top, and push the whole leather into full force.

    0.06MPa

    Temperature

    Seventy-five

    ~

    Eighty

    Temperature, time

    Two

    ~

    3min

    After vacuum drying, the green leather is placed flat and placed.

    Three

    ~

    5h


     

    (

    Three

    Hang and dry.

    Temperature control in

    Thirty-five

    ~

    Forty

    At low temperature, slowly drying, in the drying process, tanning agents, dyes and oils gradually combined with leather fibers until finally fixed.

    At the same time, the leather body is well finalized and maintained a certain elasticity.


     

    (

    Four

    Spray water resurgence.

    With a spray gun

    Thirty-five

    ~

    Forty

    The hot water is evenly sprayed on the meat surface of the dried leather, sealed with plastic film and moisture regain.

    Twelve

    ~

    18h


     

    (

    Five

    The oscillation is soft.

    According to the softness of leather, the time of oscillation and softening is decided to make the leather as soft as possible without loosening the surface.


     

    (

    Six

    The drying plate is dry.

    On the automatic flatting machine, the finished leather should be leveled without floral edges.


     

    (

    Seven

    Choose sorting and trimming.

    According to the disabled condition, the finished leather is divided into full grain and half grain leather, and the rotten edges, edges and dead ends are repaired to keep the skin shape intact.

    Finally, the cattle shoe upper leather is painted.

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